Unfortunately, there is no way to merge two accounts on Alignable. If you would like to have a second business, you can create a second Alignable account for that business and then link to your other account in your about section.
Simply log out of your current account by clicking on your name in the upper right corner and clicking "Logout".
Then, go to alignable.com and click "Sign Up" in the upper right corner:
Follow the process of creating an account. Be sure to use a unique email address for your other business and then you'll be able to service the different local areas you service.